the crust is the thin outer later of the earth where we live. well, it looks thin on the picture and it is thin relative to the other layers, but don't worry, we're not going to fall through by accident anytime soon. the crust varies from around 5km thick (in the ocean floor) to around 70km thick (on land where we live called the continental crust). the continental crust is made up of rocks that consist primarily of silica and alumina called the "sial".
the next layer of the earth is called the mantle. the mantle is much thicker than the crust at almost 3000km deep. it's made up of slightly different silicate rocks with more magnesium and iron.
the earth's outer core is made up of iron and nickel and is very hot (4400 to 5000+ degrees c). this is so hot that the iron and nickel metals are liquid! the outer core is very important to earth as it creates something called a magnetic field. the magnetic field the outer core creates goes way out in to space and makes a protective barrier around the earth that shields us from the sun's damaging solar wind.
the earth's inner core is made up of iron and nickel, just like the outer core, however, the inner core is different. the inner core is so deep within the earth that it's under immense pressure. so much pressure that, even though it is so hot, it is solid. the inner core is the hottest part of the earth, and, at over 5000 degrees c, is about as hot as the surface of the sun.